Alchemical And Later Discoveries And Uses Of Alum Mineral
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Alchemical and Modern Discoveries and Uses of Alum
Summary
Alum has fascinated alchemists and scientists for centuries. Initially identified for its potassium and sulphuric acid content, alum was better understood through the work of J.H. Pott and A.S. Marggraf, who identified alumina as a key component. Their insights laid the groundwork for its diverse applications.
Article
The presence of potassium and sulphuric acid in alum was known to early alchemists. J.H. Pott and A.S. Marggraf expanded this understanding by revealing alumina as another essential component. In his work "Lithogeognosia," Pott demonstrated that the precipitate formed when adding an alkali to an alum solution was distinct from lime and chalk, contradicting G.E. Stahl’s earlier beliefs. Marggraf further confirmed alumina’s role, highlighting its unique properties as a common clay constituent.
Interestingly, pure alum crystals do not form simply by dissolving alumina in sulphuric acid and evaporating the solution. However, when ammonia or potash is introduced, perfectly crystallized alum is deposited. Torbern Bergman noted that this crystallization occurs only with potash or ammonia, not soda or lime, pointing out that potassium sulphate is frequently associated with alum.
Alum was a significant industrial resource, primarily imported to England from the Middle East and the Papal States since the late 15th century. Its main use was as a dye-fixer for wool, a major English industry. Due to unreliable imports, there were efforts to establish domestic sources in England. Although initial 16th-century attempts failed, the industry finally took off in the 17th century in Yorkshire, using shale rich in aluminium sulphates. This contributed notably to the Industrial Revolution. Additionally, in India, alum, known as "turti," was traditionally used for water purification.
The discovery of potassium in leucite and lepidolite by M.H. Klaproth and L.N. Vauquelin led to the realization that potassium was an essential component in many ores. Realizing that alum’s crystallization depended on potash, Vauquelin suggested that potassium was a crucial ingredient. In 1797, he published an essay proving that alum is a double salt, composed of sulphuric acid, alumina, and potash.
Later, J.A. Chaptal analyzed four different types of alum: Roman, Raising, British, and a self-made variety. His findings corroborated Vauquelin’s conclusions, further unraveling alum's complex chemical nature.
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